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Beilstein J. Org. Chem. 2015, 11, 2261–2266, doi:10.3762/bjoc.11.246
Graphical Abstract
Scheme 1: NHC-carboxylates part of this study (top) and polymerization scheme with initial thermal decarboxyl...
Figure 1: Comparison of conversion over time for D4 polymerization (80 °C, bulk) using 5Me-Me-CO2. Note that ...
Scheme 2: Discussed mechanisms proposed to operate in NHC-mediated polymerization of D4 in presence/absence o...
Figure 2: Thermal activation of a 5Me-Me-CO2/BnOH/D4 (1:5:500) composition after a latency period of 72 h.